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  1. Queen Mary University of London
  2. Research
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Publications: Dr Natalia Karpukhina

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Almuhamadi J, Almusali MH, Chen X, Theocharopoulos AL, Alostath HF, Karpukhina N, Cattell MJ ( 2024 ) . Effect of TiO2 and CaO Addition on the Crystallization and Flexural Strength of Novel Leucite Glass-Ceramics . Materials vol. 17 , ( 14 )
Alhallak M, Karpukhina N, Patel M ( 2024 ) . Permeability of triamcinolone acetonide, released from mucoadhesive films, through a buccal mucosa-mimetic barrier: Permeapad™ . Dental Materials vol. 40 , ( 9 ) 1372 - 1377 .
Contreras Jaimes AT, Kirste G, Patzig C, Martins de Souza e Silva J, Massera J, Karpukhina N, Hill RG, De Pablos-Martín A et al. ( 2024 ) . Phosphate/Silicate Ratio Allows for Fine-Tuning of Bioactive Glass Crystallisation and Glass-Ceramic Microstructure . Glass Europe vol. 2 , 1 - 26 .
Kaur M, Shahid S, Karpukhina N, Anderson P, Wong FSL ( 2024 ) . Characterization of chemical reactions of silver diammine fluoride and hydroxyapatite under remineralization conditions . Frontiers in Oral Health vol. 5 ,
Alhallak M, Karpukhina N, Patel M ( 2023 ) . Triamcinolone acetonide release modelling from novel bilayer mucoadhesive films: an in vitro study . Dental Materials vol. 39 , ( 6 ) 595 - 602 .
Kusumoto H, Hill RG, Karpukhina N, Law RV ( 2023 ) . Erratum to “Magnesium substitution in calcium and strontium fluoro-phospho-aluminosilicate glasses by multinuclear 19F, 31P, 27Al, and 29Si MAS-NMR spectroscopy” [Journal of Non Crystalline Solids:X 1C (2019) 100008] . Journal of Non-Crystalline Solids X vol. 17 ,
Chen X, Wang M, Kenny C, Chen X, Karpukhina N, Hill RG ( 2022 ) . Novel Fluoride- and Chloride-containing Bioactive Glasses for Use in Air Abrasion . Journal of Dentistry vol. 125 ,
HAMED N, Karpukhina N, Gillam D, Hill R ( 2021 ) . Quantifying the Effect of Adding Alkaline Phosphatase Enzyme to Silicate/Phosphate Glass Mixtures to Enhance Bone Regeneration . Journal of Dental and Maxillofacial Research vol. 4 , ( 3 )
Jaimes ATC, Kirste G, de Pablos-Martín A, Selle S, de Souza e Silva JM, Massera J, Karpukhina N, Hill RG et al. ( 2021 ) . Nano-imaging confirms improved apatite precipitation for high phosphate/silicate ratio bioactive glasses . Scientific Reports vol. 11 , ( 1 )
Henry J, Rashwan M, Karpukhina N, Hill RG ( 2021 ) . Influence of Fluorine Content on the Crystallisation of Potassium and Barium Fluorphlogopite Glass-Ceramics . Journal of Non-Crystalline Solids vol. 559 , Article 120680 , 120680 - 120680 .
Hoxha A, Karpukhina N, Gillam DG, Bushby AJ, Patel MP ( 2020 ) . Fluoride rechargeable layered double hydroxide powders for dental applications . Applied Clay Science
Hoxha A, Gillam DG, Agha A, Karpukhina N, Bushby AJ, Patel MP ( 2020 ) . Novel fluoride rechargeable dental composites containing MgAl and CaAl layered double hydroxide (LDH) . Dental Materials
Cattell MJ, Patzig C, Bissasu S, Tsoutsos A, Karpukhina N ( 2020 ) . Nucleation efficacy and flexural strength of novel leucite glass-ceramics . Dental Materials vol. 36 , ( 5 ) 592 - 602 .
Haider A, Waseem A, Karpukhina N, Mohsin S ( 2020 ) . Strontium- and Zinc-Containing Bioactive Glass and Alginates Scaffolds . Bioengineering vol. 7 , ( 1 )
Baysan A, Sleibi A, Tappuni A, Karpukhina N, Hill R ( 2019 ) . A Comparative Evaluation of Ion Release Characteristics of Three Different Dental Varnishes containing Fluoride either with CPP-ACP or Bioactive glass . Dental Materials
Al-eesa NA, KARPUKHINA N, HILL RG, JOHAL A, WONG FSL ( 2019 ) . Bioactive glass composite for orthodontic adhesives – formation and characterisation of apatites using MAS-NMR and SEM . Dental Materials
Kusumoto H, HILL RG, KARPUKHINA N, Law RV ( 2019 ) . Magnesium substitution in calcium and strontium fluoro-phospho-aluminosilicate glasses by multinuclear 19F, 31P, 27Al, and 29Si MAS-NMR spectroscopy . Journal of Non-Crystalline Solids X
AL-KHAFAJI TJ, WONG F, FLEMING PS, KARPUKHINA N, HILL R ( 2018 ) . Novel fluoride and strontium-containing bioactive glasses for dental varnishes-design and bioactivity in Tris buffer solution . Journal of Non-Crystalline Solids vol. 503-504 , 120 - 130 .
Uwalaka C, KARPUKHINA N, CAO X, Bissasu S, WILSON R, CATTELL MJ ( 2018 ) . Effect of Sandblasting, Etching and Resin bonding on the Flexural Strength/Bonding of Novel Glass-Ceramics . Dental Materials Journal
DUMINIS T, Shahid S, KARPUKHINA N, HILL R ( 2018 ) . Predicting Refractive Index of Fluoride Containing Glasses For Aesthetic Dental Restorations . Dental Materials
Pedone A, Chen X, Hill RG, Karpukhina N ( 2018 ) . Molecular Dynamics Investigation of Halide-Containing Phospho-Silicate Bioactive Glasses . J Phys Chem B vol. 122 , ( 11 ) 2940 - 2948 .
CHEN X, CHEN X, Pedone A, Apperley D, HILL R, KARPUKHINA N ( 2018 ) . New insight into mixing fluoride and chloride in bioactive silicate glasses . Scientific Reports vol. 8 , 1316 - 1316 .
Kanwal N, Brauer DS, Earl J, Wilson RM, Karpukhina N, Hill RG ( 2017 ) . In-vitro apatite formation capacity of a bioactive glass - containing toothpaste . Journal of Dentistry vol. 68 , 51 - 58 .
Simila HO, Karpukhina N, Hill RG ( 2017 ) . Bioactivity and fluoride release of strontium and fluoride modified Biodentine . Dental Materials vol. 34 , ( 1 ) e1 - e7 .
KARPUKHINA N, Chen X, Chen X, Brauer DS, Wilson RM, Law RV, Hill RG ( 2017 ) . Sodium is not essential for high bioactivity of glasses . International Journal of Applied Glass Science
Swansbury LA, Mountjoy G, Chen X, Karpukhina N, Hill R ( 2017 ) . Modeling the Onset of Phase Separation in CaO-SiO2-CaCl2 Chlorine-Containing Silicate Glasses . J Phys Chem B vol. 121 , ( 22 ) 5647 - 5653 .
Chen X, Karpukhina N, Brauer DS, Hill RG ( 2017 ) . High chloride content calcium silicate glasses . Phys Chem Chem Phys vol. 19 , ( 10 ) 7078 - 7085 .
Kent NW, Blunn G, Karpukhina N, Davis G, de Godoy RF, Wilson RM, Coathup M, Onwordi L et al. ( 2016 ) . In vitro and in vivo study of commercial calcium phosphate cement HydroSet™ . Journal of Biomedical Materials Research Part B Applied Biomaterials vol. 106 , ( 1 ) 21 - 30 .
KARPUKHINA N, Gao Y, Law RV ( 2016 ) . Phase Segregation in Hydroxyfluorapatite Solid Solution at High Temperatures Studied by Combined XRD/Solid State NMR . RSC Advances ( 105 ) 103782 - 103790 .
Kusumoto H, Abolghasemi S, Woodfine B, Hill RG, Karpukhina N, Law RV ( 2016 ) . The effect of phosphate, fluorine, and soda content of the glass on the mechanical properties of the glass ionomer (polyalkenoate) cements . Journal of Non-Crystalline Solids vol. 449 , 94 - 99 .
Kent NW, Hill RG, Karpukhina N ( 2016 ) . A new way of forming a calcium phosphate cement using bioactive glasses as a reactive precursor . Materials Letters vol. 162 , 32 - 36 .
Chen X, Karpukhina N, Brauer DS, Hill RG ( 2015 ) . Novel Highly Degradable Chloride Containing Bioactive Glasses . Biomedical glasses vol. 1 , ( 1 )
Mansour FA, Karpukhina N, Grasso S, Wilson RM, Reece MJ, Cattell MJ ( 2015 ) . The effect of spark plasma sintering on lithium disilicate glass-ceramics . Dental Materials vol. 31 , ( 10 ) e226 - e235 .
Bingel L, Groh D, Karpukhina N, Brauer DS ( 2015 ) . Influence of dissolution medium pH on ion release and apatite formation of Bioglass® 45S5 . Materials Letters vol. 143 , 279 - 282 .
Tang HM, Shahid S, Karpukhina N, Law RV, Hill RG ( 2015 ) . Glass polyalkenoate cements based on simple CaO–Al2O3–SiO2 glasses . Materials Science and Technology vol. 31 , ( 2 ) 197 - 202 .
Kanwal N, Toms H, Hannon AC, Perras FA, Bryce DL, Karpukhina N, Abrahams I ( 2015 ) . Structure and solubility behaviour of zinc containing phosphate glasses . Journal of Materials Chemistry B vol. 3 , ( 45 ) 8842 - 8855 .
Cattell MIKE, CHEN X, Theocharopoulos T, HILL R, Karpukhina N, CATTELL MJ ( 2014 ) . WO2014207244 (A1) . no. WO2014207244 (A1 ,
CATTELL MJ, Karpukhina N, Almuhamadi J ( 2014 ) . Diopside Glass-Ceramics for Dental and Biomedical Applications . Advances in Science and Technology. vol. 96 ,
Chen X, Chen X, Brauer DS, Wilson RM, Hill RG, Karpukhina N ( 2014 ) . Novel alkali free bioactive fluorapatite glass ceramics . Journal of Non-Crystalline Solids vol. 402 , 172 - 177 .
Chen X, Brauer DS, Karpukhina N, Waite RD, Barry M, McKay IJ, Hill RG ( 2014 ) . 'Smart' acid-degradable zinc-releasing silicate glasses . Materials Letters vol. 126 , 278 - 280 .
Näfe H, Karpukhina N, Gautam D, Näfe G ( 2014 ) . Characterization of the phase mixture comprising sodium hafnate and hafnia . Zeitschrift fur Anorganische und Allgemeine Chemie
Karpukhina N, Hill RG, Law RV ( 2014 ) . ChemInform Abstract: Crystallization in Oxide Glasses — A Tutorial Review . ChemInform vol. 45 , ( 21 ) no - no .
Karpukhina N, Hill RG, Law RV ( 2014 ) . Crystallisation in oxide glasses - a tutorial review . Chem Soc Rev vol. 43 , ( 7 ) 2174 - 2186 .
Chen X, Chen X, Brauer DS, Wilson RM, Hill RG, Karpukhina N ( 2014 ) . Bioactivity of sodium free fluoride containing glasses and glass-ceramics . Materials vol. 7 , ( 8 ) 5470 - 5487 .
Chen X, Hill R, Karpukhina N ( 2014 ) . Chlorapatite Glass-Ceramics . International Journal of Applied Glass Science
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG ( 2013 ) . Effect of FA addition on bioactivity of bioactive glass coating for titanium dental implant: Part II— Composite coating . Journal of Non-Crystalline Solids vol. 364 , 99 - 106 .
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG ( 2013 ) . Effect of FA on bioactivity of bioactive glass coating for titanium dental implant. Part I: Composite powder . Journal of Non-Crystalline Solids vol. 364 , 92 - 98 .
Brauer DS, Karpukhina N, Kedia G, Bhat A, Law RV, Radecka I, Hill RG ( 2013 ) . Bactericidal strontium-releasing injectable bone cements based on bioactive glasses . Journal of the Royal Society Interface
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG ( 2013 ) . Behaviour of osteoblast-like cells cultured on titanium coated with FA/glass composite coating . JOURNAL OF NON-CRYSTALLINE SOLIDS vol. 364 , 85 - 91 .
Karpukhina N, Abo-Mosallam HA, Hill RG, Law RV ( 2013 ) . Effect of Sodium, potassium and zinc substitutions in lithium disilicate glass and glass-ceramics . PHYSICS AND CHEMISTRY OF GLASSES-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART B vol. 54 , ( 2 ) 76 - 83 .
Mohammed NR, Kent NW, Lynch RJM, Karpukhina N, Hill R, Anderson P ( 2013 ) . Effects of fluoride on in vitro enamel demineralization analyzed by ¹⁹F MAS-NMR . Caries Res vol. 47 , ( 5 ) 421 - 428 .
Lynch E, Brauer DS, Karpukhina N, Gillam DG, Hill RG ( 2012 ) . Multi-component bioactive glasses of varying fluoride content for treating dentin hypersensitivity . Dent Mater vol. 28 , ( 2 ) 168 - 178 .
Zainuddin N, Karpukhina N, Law RV, Hill RG ( 2012 ) . Characterisation of a remineralising Glass Carbomer® ionomer cement by MAS-NMR Spectroscopy . DENTAL MATERIALS vol. 28 , ( 10 ) 1051 - 1058 .
Fredholm YC, Karpukhina N, Brauer DS, Jones JR, Law RV, Hill RG ( 2012 ) . Influence of strontium for calcium substitution in bioactive glasses on degradation, ion release and apatite formation . JOURNAL OF THE ROYAL SOCIETY INTERFACE vol. 9 , ( 70 ) 880 - 889 .
Fujikura K, Karpukhina N, Kasuga T, Brauer DS, Hill RG, Law RV ( 2012 ) . Influence of strontium substitution on structure and crystallisation of Bioglass® 45S5 . JOURNAL OF MATERIALS CHEMISTRY vol. 22 , ( 15 ) 7395 - 7402 .
O'Donnell M, Hill RG, Karpukhina N, Law RV ( 2011 ) . Real time neutron diffraction and NMR of the Empress II glass-ceramic system . Dental Materials vol. 27 , ( 10 ) 990 - 996 .
Hill RG, O'Donnell MD, Law RV, Karpukhina N, Cochrane B, Tulyaganov DU ( 2010 ) . The early stages of nucleation and crystallisation of an apatite glass-ceramic: Evidence for nano-scale crystallisation . JOURNAL OF NON-CRYSTALLINE SOLIDS . vol. 356 , 2935 - 2941 .
Brauer DS, Karpukhina N, Law RV, Hill RG ( 2010 ) . Effect of TiO2 addition on structure, solubility and crystallisation of phosphate invert glasses for biomedical applications . JOURNAL OF NON-CRYSTALLINE SOLIDS . vol. 356 , 2626 - 2633 .
O'Donnell MD, Karpukhina N, Calver AI, Law RV, Bubb N, Stamboulis A, Hill RG ( 2010 ) . Real time neutron diffraction and solid state NMR of high strength apatite-mullite glass ceramic . JOURNAL OF NON-CRYSTALLINE SOLIDS . vol. 356 , 2693 - 2698 .
Fredholm YC, Karpukhina N, Law RV, Hill RG ( 2010 ) . Strontium containing bioactive glasses: Glass structure and physical properties . JOURNAL OF NON-CRYSTALLINE SOLIDS . vol. 356 , 2546 - 2551 .
Brauer DS, Karpukhina N, O'Donnell MD, Law RV, Hill RG ( 2010 ) . Fluoride-containing bioactive glasses: effect of glass design and structure on degradation, pH and apatite formation in simulated body fluid . Acta Biomater vol. 6 , ( 8 ) 3275 - 3282 .
Brauer DS, Karpukhina N, Law RV, Hill RG ( 2010 ) . Effect of TiO2 addition on structure, solubility and crystallisation of phosphate derived invert glasses for biomedical applications . Journal of Non-Crystalline Solids vol. 356 , ( 44-49 ) 2626 - 2633 .
Abo-Mosallam HA, Hill RG, Karpukhina N, Law RV ( 2010 ) . MAS-NMR studies of glasses and glass-ceramics based on a clinopyroxene-fluorapatite system . Journal of Materials Chemistry vol. 20 , ( 4 ) 790 - 797 .
Munhoz T, Karpukhina N, Hill RG, Law RV, De Almeida LH ( 2010 ) . Setting of commercial glass ionomer cement Fuji IX by 27Al and 19F MAS-NMR . Journal of Dentistry vol. 38 , ( 4 ) 325 - 330 .
Hill RG, O'Donnell MD, Law RV, Karpukhina N, Cochrane B, Tulyaganov D ( 2010 ) . The early stages of nucleation and crystallisation of an apatite glass-ceramic: Evidence for nano-scale crystallisation . Journal of Non-Crystalline Solids vol. 356 , ( 52-54 ) 2935 - 2941 .
Zainuddin N, Karpukhina N, Hill RG, Law RV ( 2009 ) . A long-term study on the setting reaction of glass ionomer cements by (27)Al MAS-NMR spectroscopy . Dent Mater vol. 25 , ( 3 ) 290 - 295 .
Brauer DS, Karpukhina N, Law RV, Hill RG ( 2009 ) . Structure of fluoride-containing bioactive glasses . J MATER CHEM vol. 19 , ( 31 ) 5629 - 5636 .
Zainuddin N, Karpukhina N, Law RV, Hill RG ( 2008 ) . A long term study on the setting reaction of glass polyalkenoate cements by <sup>27</sup>Al MAS-NMR spectroscopy . 8th World Biomaterials Congress 2008 . vol. 3 ,
Brauer DS, Karpukhina N, Seah D, Hill RG ( 2008 ) . Fluoride-containing bioactive glasses for polyalkenoate bone cements . 8th World Biomaterials Congress 2008 . vol. 2 ,
Brauer DS, Karpukhina N, Seah D, Law RV, Hill RG ( 2008 ) . Fluoride-containing bioactive glasses . GLASS - THE CHALLENGE FOR THE 21ST CENTURY . Editors: Liska, M, Galusek, D, Klement, R, Petruskova, V et al. , vol. 39-40 , 299 - 304 .
Karpukhina N, Law RV, Hill RG ( 2008 ) . Solid state NMR study of calcium fluoroaluminosilicate glasses . GLASS - THE CHALLENGE FOR THE 21ST CENTURY . Editors: Liska, M, Galusek, D, Klement, R, Petruskova, V et al. , vol. 39-40 , 25 - 30 .
Karpukhina NG, Werner-Zwanziger U, Zwanziger JW, Kiprianov AA ( 2007 ) . Preferential Binding of Fluorine to Aluminum in High Peralkaline Aluminosilicate Glasses . The Journal of Physical Chemistry B vol. 111 , ( 35 ) 10413 - 10420 .
Nafe H, Karpukhina N ( 2007 ) . Na-modified cubic zirconia-link between sodium zirconate and zirconia in the Na2O-ZrO2 phase diagram . J AM CERAM SOC vol. 90 , ( 5 ) 1597 - 1602 .
Kiprianov AA, Karpukhina NG ( 2006 ) . Oxyhalide silicate glasses . Glass Physics and Chemistry vol. 32 , ( 1 ) 1 - 27 .
Kiprianov AA, Karpukhina NG, Molodozhen VA ( 2004 ) . Investigation into the influence of chloride additives on the properties of alkali silicate glasses . Glass Physics and Chemistry vol. 30 , ( 4 ) 325 - 332 .
Kiprianov AA, Karpukhina NG, Molodozhen VA ( 2004 ) . Investigation into the influence of chloride additives on the properties of alkali silicate glasses . Fizika i Khimiya Stekla vol. 30 , ( 4 ) 440 - 451 .
Karpukhina NG, Kiprianov AA ( 2001 ) . Electrode properties of some fluorine-containing alkali silicate glasses . Fizika i Khimiya Stekla vol. 27 , ( 1 ) 101 - 108 .
Kiprianov AA, Karpukhina NG ( 2001 ) . Influence of fluoride additions on electric characteristics of alkali silicate electrode glasses . Fizika i Khimiya Stekla vol. 27 , ( 1 ) 108 - 116 .
Karpukhina NG, Kiprianov AA ( 2001 ) . Electrode properties of fluorine-containing alkali silicate glasses . Glass Physics and Chemistry vol. 27 , ( 1 ) 69 - 73 .
Kiprianov AA, Karpukhina NG ( 2001 ) . Influence of fluoride additives on the electrical characteristics of alkali silicate electrode glasses . Glass Physics and Chemistry vol. 27 , ( 1 ) 74 - 79 .
Kiprianov AA, Golubko NV, Karpukhina NG, Molodozhen VA ( 1998 ) . Thermal, electrical, and potentiometric characteristics of sodium aluminosilicate glasses with fluoride additives . Glass Physics and Chemistry vol. 24 , ( 4 ) 350 - 354 .
Kiprianov AA, Karpukhina NG ( 1997 ) . Potentiometric determination of fluoride content in alkali-aluminosilicate oxyhalide glasses . Russian Journal of Applied Chemistry vol. 70 , ( 7 ) 1144 - 1146 .
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