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Publications:  Dr Natalia Karpukhina

Cattell MJ, Patzig C, Bissasu S, Tsoutsos A, Karpukhina N(2020). Nucleation efficacy and flexural strength of novel leucite glass-ceramics. Dental Materials vol. 36, (5) 592-602.
10.1016/j.dental.2020.03.017
https://qmro.qmul.ac.uk/xmlui/handle/123456789/66395
Haider A, Waseem A, Karpukhina N, Mohsin S(2020). Strontium- and Zinc-Containing Bioactive Glass and Alginates Scaffolds. Bioengineering vol. 7, (1)
10.3390/bioengineering7010010
https://qmro.qmul.ac.uk/xmlui/handle/123456789/62542
Hoxha A, Gillam DG, Agha A, Karpukhina N, Bushby AJ, Patel MP(2020). Novel fluoride rechargeable dental composites containing MgAl and CaAl layered double hydroxide (LDH). Dental Materials
10.1016/j.dental.2020.04.011
Baysan A, Sleibi A, Tappuni A, Karpukhina N, Hill R(2019). A Comparative Evaluation of Ion Release Characteristics of Three Different Dental Varnishes containing Fluoride either with CPP-ACP or Bioactive glass. Dental Materials
10.1016/j.dental.2019.08.113
https://qmro.qmul.ac.uk/xmlui/handle/123456789/61423
Al-eesa NA, KARPUKHINA N, HILL RG, JOHAL A, WONG FSL(2019). Bioactive glass composite for orthodontic adhesives – formation and characterisation of apatites using MAS-NMR and SEM. Dental Materials
10.1016/j.dental.2019.02.010
https://qmro.qmul.ac.uk/xmlui/handle/123456789/56051
Kusumoto H, HILL RG, KARPUKHINA N, Law RV(2019). Magnesium substitution in calcium and strontium fluoro-phospho-aluminosilicate glasses by multinuclear 19F, 31P, 27Al, and 29Si MAS-NMR spectroscopy. Journal of Non-Crystalline Solids X
10.1016/j.nocx.2019.100008
https://qmro.qmul.ac.uk/xmlui/handle/123456789/55560
AL-KHAFAJI TJ, WONG F, FLEMING PS, KARPUKHINA N, HILL R(2018). Novel fluoride and strontium-containing bioactive glasses for dental varnishes-design and bioactivity in Tris buffer solution. Journal of Non-Crystalline Solids vol. 503-504, 120-130.
10.1016/j.jnoncrysol.2018.09.037
https://qmro.qmul.ac.uk/xmlui/handle/123456789/49765
Uwalaka C, KARPUKHINA N, CAO X, Bissasu S, WILSON R, CATTELL MJ(2018). Effect of Sandblasting, Etching and Resin bonding on the Flexural Strength/Bonding of Novel Glass-Ceramics. Dental Materials Journal
10.1016/j.dental.2018.07.001
https://qmro.qmul.ac.uk/xmlui/handle/123456789/43026
DUMINIS T, Shahid S, KARPUKHINA N, HILL R(2018). Predicting Refractive Index of Fluoride Containing Glasses For Aesthetic Dental Restorations. Dental Materials
10.1016/j.dental.2018.01.024
https://qmro.qmul.ac.uk/xmlui/handle/123456789/48883
Pedone A, Chen X, Hill RG, Karpukhina N(2018). Molecular Dynamics Investigation of Halide-Containing Phospho-Silicate Bioactive Glasses. J Phys Chem B vol. 122, (11) 2940-2948.
10.1021/acs.jpcb.8b00547
https://qmro.qmul.ac.uk/xmlui/handle/123456789/36483
CHEN X, CHEN X, Pedone A, Apperley D, HILL R, KARPUKHINA N(2018). New insight into mixing fluoride and chloride in bioactive silicate glasses. Scientific Reports vol. 8, 1316-1316.
10.1038/s41598-018-19544-2
https://qmro.qmul.ac.uk/xmlui/handle/123456789/36393
Simila HO, Karpukhina N, Hill RG(2018). Bioactivity and fluoride release of strontium and fluoride modified Biodentine. Dental Materials vol. 34, (1) e1-e7.
10.1016/j.dental.2017.10.005
https://qmro.qmul.ac.uk/xmlui/handle/123456789/28700
Kent NW, Blunn G, Karpukhina N, Davis G, de Godoy RF, Wilson RM, Coathup M, Onwordi L et al.(2018). In vitro and in vivo study of commercial calcium phosphate cement HydroSet™. Journal of Biomedical Materials Research - Part B Applied Biomaterials vol. 106, (1) 21-30.
10.1002/jbm.b.33809
https://qmro.qmul.ac.uk/xmlui/handle/123456789/36423
Kanwal N, Brauer DS, Earl J, Wilson RM, Karpukhina N, Hill RG(2018). In-vitro apatite formation capacity of a bioactive glass - containing toothpaste. Journal of Dentistry vol. 68, 51-58.
10.1016/j.jdent.2017.10.015
https://qmro.qmul.ac.uk/xmlui/handle/123456789/28843
KARPUKHINA N, Chen X, Chen X, Brauer DS, Wilson RM, Law RV, Hill RG(2017). Sodium is not essential for high bioactivity of glasses. International Journal of Applied Glass Science
10.1111/ijag.12323
https://qmro.qmul.ac.uk/xmlui/handle/123456789/26383
Swansbury LA, Mountjoy G, Chen X, Karpukhina N, Hill R(2017). Modeling the Onset of Phase Separation in CaO-SiO2-CaCl2 Chlorine-Containing Silicate Glasses. J Phys Chem B vol. 121, (22) 5647-5653.
10.1021/acs.jpcb.7b02986
https://qmro.qmul.ac.uk/xmlui/handle/123456789/23587
Chen X, Karpukhina N, Brauer DS, Hill RG(2017). High chloride content calcium silicate glasses. Phys Chem Chem Phys vol. 19, (10) 7078-7085.
10.1039/c6cp07905a
https://qmro.qmul.ac.uk/xmlui/handle/123456789/22348
KARPUKHINA N, Gao Y, Law RV(2016). Phase Segregation in Hydroxyfluorapatite Solid Solution at High Temperatures Studied by Combined XRD/Solid State NMR. RSC Advances (105) 103782-103790.
10.1039/C6RA17161C
https://qmro.qmul.ac.uk/xmlui/handle/123456789/17362
Kusumoto H, Abolghasemi S, Woodfine B, Hill RG, Karpukhina N, Law RV(2016). The effect of phosphate, fluorine, and soda content of the glass on the mechanical properties of the glass ionomer (polyalkenoate) cements. Journal of Non-Crystalline Solids vol. 449, 94-99.
10.1016/j.jnoncrysol.2016.06.036
https://qmro.qmul.ac.uk/xmlui/handle/123456789/15014
Kent NW, Hill RG, Karpukhina N(2016). A new way of forming a calcium phosphate cement using bioactive glasses as a reactive precursor. Materials Letters vol. 162, 32-36.
10.1016/j.matlet.2015.09.099
Bingel L, Groh D, Karpukhina N, Brauer DS(2015). Influence of dissolution medium pH on ion release and apatite formation of Bioglass<sup>®</sup> 45S5. Materials Letters vol. 143, 279-282.
10.1016/j.matlet.2014.12.124
https://qmro.qmul.ac.uk/xmlui/handle/123456789/7201
Tang HM, Shahid S, Karpukhina N, Law RV, Hill RG(2015). Glass polyalkenoate cements based on simple CaO-Al<inf>2</inf>O<inf>3</inf>-SiO<inf>2</inf> glasses. Materials Science and Technology (United Kingdom) vol. 31, (2) 197-202.
10.1179/1743284714Y.0000000601
https://qmro.qmul.ac.uk/xmlui/handle/123456789/7017
Chen X, Karpukhina N, Brauer DS, Hill RG(2015). Novel highly degradable chloride containing bioactive glasses. Biomedical Glasses vol. 1, (1) 108-118.
10.1515/bglass-2015-0010
Kanwal N, Toms H, Hannon AC, Perras FA, Bryce DL, Karpukhina N, Abrahams I(2015). Structure and solubility behaviour of zinc containing phosphate glasses. Journal of Materials Chemistry B vol. 3, (45) 8842-8855.
10.1039/c4tb01504e
https://qmro.qmul.ac.uk/xmlui/handle/123456789/11673
Al Mansour F, Karpukhina N, Grasso S, Wilson RM, Reece MJ, Cattell MJ(2015). The effect of spark plasma sintering on lithium disilicate glass-ceramics. Dental Materials vol. 31, (10) e226-e235.
10.1016/j.dental.2015.07.001
Cattell MIKE, CHEN X, Theocharopoulos T, HILL R, Karpukhina N, CATTELL MJ (2014). WO2014207244 (A1). no. WO2014207244 (A1,
https://qmro.qmul.ac.uk/xmlui/handle/123456789/18022
CATTELL MJ, Karpukhina N, Almuhamadi J(2014). Diopside Glass-Ceramics for Dental and Biomedical Applications. Advances in Science and Technology. vol. 96,
10.4028/www.scientific.net/AST.96.15
https://qmro.qmul.ac.uk/xmlui/handle/123456789/11308
Chen X, Chen X, Brauer DS, Wilson RM, Hill RG, Karpukhina N(2014). Novel alkali free bioactive fluorapatite glass ceramics. Journal of Non-Crystalline Solids vol. 402, 172-177.
10.1016/j.jnoncrysol.2014.05.025
Chen X, Brauer DS, Karpukhina N, Waite RD, Barry M, McKay IJ, Hill RG(2014). 'Smart' acid-degradable zinc-releasing silicate glasses. Materials Letters vol. 126, 278-280.
10.1016/j.matlet.2014.04.009
Näfe H, Karpukhina N, Gautam D, Näfe G(2014). Characterization of the phase mixture comprising sodium hafnate and hafnia. Zeitschrift fur Anorganische und Allgemeine Chemie
10.1002/zaac.201400097
Karpukhina N, Hill RG, Law RV(2014). Crystallisation in oxide glasses - a tutorial review. Chem Soc Rev vol. 43, (7) 2174-2186.
10.1039/c3cs60305a
Chen X, Chen X, Brauer DS, Wilson RM, Hill RG, Karpukhina N(2014). Bioactivity of sodium free fluoride containing glasses and glass-ceramics. Materials vol. 7, (8) 5470-5487.
10.3390/ma7085470
https://qmro.qmul.ac.uk/xmlui/handle/123456789/56733
Chen X, Hill R, Karpukhina N(2014). Chlorapatite Glass-Ceramics. International Journal of Applied Glass Science
10.1111/ijag.12082
Karpukhina N, Abo-Mosallam HA, Hill RG, Law RV(2013). Effect of Sodium, potassium and zinc substitutions in lithium disilicate glass and glass-ceramics. PHYSICS AND CHEMISTRY OF GLASSES-EUROPEAN JOURNAL OF GLASS SCIENCE AND TECHNOLOGY PART B vol. 54, (2) 76-83.
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG(2013). Behaviour of osteoblast-like cells cultured on titanium coated with FA/glass composite coating. JOURNAL OF NON-CRYSTALLINE SOLIDS vol. 364, 85-91.
10.1016/j.jnoncrysol.2012.12.041
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG(2013). Effect of FA addition on bioactivity of bioactive glass coating for titanium dental implant: Part II— Composite coating. Journal of Non-Crystalline Solids vol. 364, 99-106.
10.1016/j.jnoncrysol.2012.11.046
Al-Noaman A, Karpukhina N, Rawlinson SCF, Hill RG(2013). Effect of FA on bioactivity of bioactive glass coating for titanium dental implant. Part I: Composite powder. Journal of Non-Crystalline Solids vol. 364, 92-98.
10.1016/j.jnoncrysol.2012.11.051
Brauer DS, Karpukhina N, Kedia G, Bhat A, Law RV, Radecka I, Hill RG(2013). Bactericidal strontium-releasing injectable bone cements based on bioactive glasses. Journal of the Royal Society Interface
10.1098/rsif.2012.0647
Mohammed NR, Kent NW, Lynch RJM, Karpukhina N, Hill R, Anderson P(2013). Effects of fluoride on in vitro enamel demineralization analyzed by ¹⁹F MAS-NMR. Caries Res vol. 47, (5) 421-428.
10.1159/000350171
Zainuddin N, Karpukhina N, Law RV, Hill RG(2012). Characterisation of a remineralising Glass Carbomer (R) ionomer cement by MAS-NMR Spectroscopy. DENTAL MATERIALS vol. 28, (10) 1051-1058.
10.1016/j.dental.2012.06.011
Fredholm YC, Karpukhina N, Brauer DS, Jones JR, Law RV, Hill RG(2012). Influence of strontium for calcium substitution in bioactive glasses on degradation, ion release and apatite formation. JOURNAL OF THE ROYAL SOCIETY INTERFACE vol. 9, (70) 880-889.
10.1098/rsif.2011.0387
Lynch E, Brauer DS, Karpukhina N, Gillam DG, Hill RG(2012). Multi-component bioactive glasses of varying fluoride content for treating dentin hypersensitivity. Dent Mater vol. 28, (2) 168-178.
10.1016/j.dental.2011.11.021
Fujikura K, Karpukhina N, Kasuga T, Brauer DS, Hill RG, Law RV(2012). Influence of strontium substitution on structure and crystallisation of Bioglass (R) 45S5. JOURNAL OF MATERIALS CHEMISTRY vol. 22, (15) 7395-7402.
10.1039/c2jm14674f
O'Donnell M, Hill RG, Karpukhina N, Law RV(2011). Real time neutron diffraction and NMR of the Empress II glass-ceramic system. Dental Materials vol. 27, (10) 990-996.
10.1016/j.dental.2011.06.005
https://qmro.qmul.ac.uk/xmlui/handle/123456789/2202
Hill RG, O'Donnell MD, Law RV, Karpukhina N, Cochrane B, Tulyaganov DU (2010). The early stages of nucleation and crystallisation of an apatite glass-ceramic: Evidence for nano-scale crystallisation. JOURNAL OF NON-CRYSTALLINE SOLIDS. vol. 356, 2935-2941.
10.1016/j.jnoncrysol.2010.05.102
Brauer DS, Karpukhina N, Law RV, Hill RG (2010). Effect of TiO2 addition on structure, solubility and crystallisation of phosphate invert glasses for biomedical applications. JOURNAL OF NON-CRYSTALLINE SOLIDS. vol. 356, 2626-2633.
10.1016/j.jnoncrysol.2010.03.022
https://qmro.qmul.ac.uk/xmlui/handle/123456789/1116
O'Donnell MD, Karpukhina N, Calver AI, Law RV, Bubb N, Stamboulis A, Hill RG (2010). Real time neutron diffraction and solid state NMR of high strength apatite-mullite glass ceramic. JOURNAL OF NON-CRYSTALLINE SOLIDS. vol. 356, 2693-2698.
10.1016/j.jnoncrysol.2010.08.038
Fredholm YC, Karpukhina N, Law RV, Hill RG (2010). Strontium containing bioactive glasses: Glass structure and physical properties. JOURNAL OF NON-CRYSTALLINE SOLIDS. vol. 356, 2546-2551.
10.1016/j.jnoncrysol.2010.06.078
Brauer DS, Karpukhina N, O'Donnell MD, Law RV, Hill RG(2010). Fluoride-containing bioactive glasses: effect of glass design and structure on degradation, pH and apatite formation in simulated body fluid. Acta Biomater vol. 6, (8) 3275-3282.
10.1016/j.actbio.2010.01.043
https://qmro.qmul.ac.uk/xmlui/handle/123456789/1118
Brauer DS, Karpukhina N, Law RV, Hill RG(2010). Effect of TiO2 addition on structure, solubility and crystallisation of phosphate derived invert glasses for biomedical applications. Journal of Non-Crystalline Solids vol. 356, (44-49) 2626-2633.
10.1016/j.jnoncrysol.2010.03.022.
Abo-Mosallam HA, Hill RG, Karpukhina N, Law RV(2010). MAS-NMR studies of glasses and glass-ceramics based on a clinopyroxene-fluorapatite system. Journal of Materials Chemistry vol. 20, (4) 790-797.
10.1039/b915573b
https://qmro.qmul.ac.uk/xmlui/handle/123456789/2405
Munhoz T, Karpukhina N, Hill RG, Law RV, De Almeida LH(2010). Setting of commercial glass ionomer cement Fuji IX by 27Al and 19F MAS-NMR. Journal of Dentistry vol. 38, (4) 325-330.
10.1016/j.jdent.2009.12.005
https://qmro.qmul.ac.uk/xmlui/handle/123456789/2203
Hill RG, O'Donnell MD, Law RV, Karpukhina N, Cochrane B, Tulyaganov D(2010). The early stages of nucleation and crystallisation of an apatite glass-ceramic: Evidence for nano-scale crystallisation. Journal of Non-Crystalline Solids vol. 356, (52-54) 2935-2941.
10.1016/j.jnoncrysol.2010.05.102
Zainuddin N, Karpukhina N, Hill RG, Law RV(2009). A long-term study on the setting reaction of glass ionomer cements by (27)Al MAS-NMR spectroscopy. Dent Mater vol. 25, (3) 290-295.
10.1016/j.dental.2008.07.008
Brauer DS, Karpukhina N, Law RV, Hill RG(2009). Structure of fluoride-containing bioactive glasses. J MATER CHEM vol. 19, (31) 5629-5636.
10.1039/b900956f
https://qmro.qmul.ac.uk/xmlui/handle/123456789/1100
Zainuddin N, Karpukhina N, Law RV, Hill RG (2008). A long term study on the setting reaction of glass polyalkenoate cements by <sup>27</sup>Al MAS-NMR spectroscopy. 8th World Biomaterials Congress 2008. vol. 3,
Brauer DS, Karpukhina N, Seah D, Hill RG (2008). Fluoride-containing bioactive glasses for polyalkenoate bone cements. 8th World Biomaterials Congress 2008. vol. 2,
Brauer DS, Karpukhina N, Seah D, Law RV, Hill RG (2008). Fluoride-containing bioactive glasses. GLASS - THE CHALLENGE FOR THE 21ST CENTURY. Editors: Liska, M, Galusek, D, Klement, R, Petruskova, V et al., vol. 39-40, 299-304.
10.4028/www.scientific.net/AMR.39-40.299
Karpukhina N, Law RV, Hill RG (2008). Solid state NMR study of calcium fluoroaluminosilicate glasses. GLASS - THE CHALLENGE FOR THE 21ST CENTURY. Editors: Liska, M, Galusek, D, Klement, R, Petruskova, V et al., vol. 39-40, 25-30.
10.4028/www.scientific.net/AMR.39-40.25
Karpukhina NG, Werner-Zwanziger U, Zwanziger JW, Kiprianov AA(2007). Preferential binding of fluorine to aluminum in high pecalkaline aluminosilicate glasses. Journal of Physical Chemistry B vol. 111, (35) 10413-10420.
10.1021/jp073687j
Nafe H, Karpukhina N(2007). Na-modified cubic zirconia-link between sodium zirconate and zirconia in the Na2O-ZrO2 phase diagram. J AM CERAM SOC vol. 90, (5) 1597-1602.
10.1111/j.1551-2916.2007.01616
Kiprianov AA, Karpukhina NG(2006). Oxyhalide silicate glasses. Glass Physics and Chemistry vol. 32, (1) 1-27.
10.1134/S1087659606010019
Kiprianov AA, Karpukhina NG, Molodozhen VA(2004). Investigation into the influence of chloride additives on the properties of alkali silicate glasses. Glass Physics and Chemistry vol. 30, (4) 325-332.
10.1023/B:GPAC.0000038704.68182.72
Kiprianov AA, Karpukhina NG, Molodozhen VA(2004). Investigation into the influence of chloride additives on the properties of alkali silicate glasses. Fizika i Khimiya Stekla vol. 30, (4) 440-451.
Karpukhina NG, Kiprianov AA(2001). Electrode properties of some fluorine-containing alkali silicate glasses. Fizika i Khimiya Stekla vol. 27, (1) 101-108.
Kiprianov AA, Karpukhina NG(2001). Influence of fluoride additions on electric characteristics of alkali silicate electrode glasses. Fizika i Khimiya Stekla vol. 27, (1) 108-116.
Karpukhina NG, Kiprianov AA(2001). Electrode properties of fluorine-containing alkali silicate glasses. Glass Physics and Chemistry vol. 27, (1) 69-73.
10.1023/A:1009516005773
Kiprianov AA, Karpukhina NG(2001). Influence of fluoride additives on the electrical characteristics of alkali silicate electrode glasses. Glass Physics and Chemistry vol. 27, (1) 74-79.
10.1023/A:1009568022611
Kiprianov AA, Golubko NV, Karpukhina NG, Molodozhen VA(1998). Thermal, electrical, and potentiometric characteristics of sodium aluminosilicate glasses with fluoride additives. Glass Physics and Chemistry vol. 24, (4) 350-354.
Kiprianov AA, Karpukhina NG(1997). Potentiometric determination of fluoride content in alkali-aluminosilicate oxyhalide glasses. Russian Journal of Applied Chemistry vol. 70, (7) 1144-1146.
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